Electrospray mass spectrometric, proton NMR, UV-titrametric, electrochemical and X-ray crystallographic studies have shown that, in the presence of cobalt(II), 2,3-bis(2,2′-bipyrid-6-yl)pyrazine self-assembles to form a dimeric metallocyclophane which is also stable in solution.
F. Heirtzler and T. Weyhermüller, J. Chem. Soc., Dalton Trans., 1997, 3653 DOI: 10.1039/A705598F
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