Issue 20, 1997
From the journal:

Chemical Communications

Synthesis and structure of [Sn(mit)6Cu4]; a [SnCu4] cage supported by Sn–Cu cluster bonding [mit = (CH)2N(Me)C([horiz bar, double dot above]S)[horiz bar, double dot above]N]

Robert E. Allan,   Julie S. Palmer,   Marta E. G. Mosquera,   Jeremy M. Rawson,   Andrew E. H. Wheatley,   Dominic S. Wright,   Alan Bashall  and  Mary McPartlin  

Abstract

The reaction of [Sn(mit)2]n with CuCl gives the heterobimetallic complex [{Sn(mit)6Cu4] 1, in which the hypho-hexagonal-bipyramidal [SnCu4] core is stabilised by SnII–CuI cluster bonding between the endo lone pair of the Sn centre and the tetrahedral Cu4 fragment.

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Article information

DOI
https://doi.org/10.1039/A705220K
Article type
Paper

Chem. Commun., 1997, 1975-1976

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Synthesis and structure of [Sn(mit)6Cu4]; a [SnCu4] cage supported by Sn–Cu cluster bonding [mit = (CH)2N(Me)C([horiz bar, double dot above]S)[horiz bar, double dot above]N]

R. E. Allan, J. S. Palmer, M. E. G. Mosquera, J. M. Rawson, A. E. H. Wheatley, D. S. Wright, A. Bashall and M. McPartlin, Chem. Commun., 1997, 1975 DOI: 10.1039/A705220K

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