Issue 20, 1997
From the journal:

Chemical Communications

‘Soft–soft’ halogen–halogen interactions in solid ion pairs of solvent-free Pri3PCl2 and CH2Cl2-solvated Pri3PBr2: structural features of chloro- and bromo-triisopropylphosphonium salts

Frank Ruthe  

Abstract

An X-ray crystallographic study of solvent-free Pri3PCl2 and dichloromethane-solvated Pri3PBr2 reveals that both halogenophosphonium halides exist as monomeric ion pairs Pri3P+–X···X–; elongations of P–Cl and P–Br bonds are associated with Cl···Cl and Br···Br interactions.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/A704684G
Article type
Paper

Chem. Commun., 1997, 1947-1948

Permissions

Request permissions

‘Soft–soft’ halogen–halogen interactions in solid ion pairs of solvent-free Pri3PCl2 and CH2Cl2-solvated Pri3PBr2: structural features of chloro- and bromo-triisopropylphosphonium salts

F. Ruthe, Chem. Commun., 1997, 1947 DOI: 10.1039/A704684G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements