Issue 18, 1997

A cage ligand with three convergent pyridine donors

Abstract

A macrocyclic malonic ester condensation with pyridine building blocks leads to the new bicyclic host molecule 1 with defined cavity size, the X-ray structure analysis of which reveals three convergent nitrogen donor centres; in radiotracer phase-transfer measurements 1 turns out to be remarkably selective for Ag I cations while discriminating against Cu I and Cu II cations.

Article information

Article type
Paper

Chem. Commun., 1997, 1809-1810

A cage ligand with three convergent pyridine donors

F. Vögtle, S. Ibach, M. Nieger, C. Chartroux, T. Krüger, H. Stephan and K. Gloe, Chem. Commun., 1997, 1809 DOI: 10.1039/A703715E

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