Issue 20, 1997
From the journal:

Chemical Communications

The reduction of Nb2Cl6(tmeda)2 by R2NLi. Formation of a diamagnetic niobium(II) cluster with short Nb–Nb triple bond and amide C–N bond cleavage

Maryam Tayebani,   Aparna Kasani  and  Khalil Feghali  

Abstract

Reduction of trivalent Nb2Cl6(tmeda)2 with either lithium diisopropylamide or n-butyllithium yields a novel NbII cluster which performs oxidative addition into the amide C–N bond.

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Article information

DOI
https://doi.org/10.1039/A703280C
Article type
Paper

Chem. Commun., 1997, 2001-2002

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The reduction of Nb2Cl6(tmeda)2 by R2NLi. Formation of a diamagnetic niobium(II) cluster with short Nb–Nb triple bond and amide C–N bond cleavage

M. Tayebani, A. Kasani and K. Feghali, Chem. Commun., 1997, 2001 DOI: 10.1039/A703280C

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