Template synthesis of [Cr(en)3][Te6]: a novel polytelluride with a framework structure, whose cavities are filled with a [Cr(en)3]3+ template
Abstract
[Cr(en)
3
][Te
6
] (en = ethylenediamine) is obtained
by a template synthesis under solvothermal conditions from
Cr(CO)
6
and BaTe
4
; its crystal structure contains a
polymeric Te
6
3-
framework whose pores contain
the Cr(en)
3
3+
template;
[Cr(en)
3
][Te
6
] is the first chalcogenide with a
porous three-dimensional framework structure.
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