Ethane reacts in the presence of Fe- and Mn-promoted sulfated ZrO2 to form butane, ethene, methane and H2 at temperatures ![[gt-or-equal]](https://www.rsc.org/images/entities/char_2a7e.gif)
473 K; the data indicate autocatalysis with carbocation intermediates as in superacid solution chemistry.
T. Cheung and B. C. Gates, Chem. Commun., 1996, 1937 DOI: 10.1039/CC9960001937
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