Infrared multiphoton decomposition of 2-chloroethenylsilane is dominated by dehydrochlorination and by decomposition of the intermediary ethynylsilane, and it affords a solid material consisting of an Si/C/H polymer and silicon carbide. The content of the latter can be increased by using a high-energy fluence of laser radiation.
M. Santos, L. Díaz, Z. Bastl, V. Hulínský, M. Urbanová, J. Vítek and J. Pola, J. Mater. Chem., 1996, 6, 975 DOI: 10.1039/JM9960600975
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