Issue 21, 1996

Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene and -allylbenzene; evidence for novel carbon–carbon double and triple bond cleavage and alkyne insertion reactions

Abstract

Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene or -allylbenzene leads to either novel reorganisation reactions involving cleavage of carbon–carbon double and triple bonds, or unusual insertion reactions by PhC2Ph into carbon–hydrogen bonds.

Article information

Article type
Paper

Chem. Commun., 1996, 2431-2432

Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene and -allylbenzene; evidence for novel carbon–carbon double and triple bond cleavage and alkyne insertion reactions

G. A. Cairns, N. Carr, M. Green and M. F. Mahon, Chem. Commun., 1996, 2431 DOI: 10.1039/CC9960002431

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