The diruthenium(II) complex [Ru2(µ-Cl)(µ-H)(µ-Me2SO)-Cl2(Me2SO)4]·2CH2Cl2 is prepared from [RuCl2(Me2SO)4] in methanol in the presence of Na2(xdk)[H2xdk =m-xylenediamine bis(Kemp's triacid imide)] and characterized by X-ray crystallography which reveals an unprecedented S,O-bidentate bridging Me2SO ligand.
T. Tanase, T. Aiko and Y. Yamamoto, Chem. Commun., 1996, 2341 DOI: 10.1039/CC9960002341
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