Chelated glycinate on cobalt(III) is readily oxidized to 2-iminoacetate to give a useful synthon for stereoselective syntheses of α-amino acids by the addition of carbanions and through asymmetric transformations of the second kind.
L. Bendahl, A. Hammershøi, D. K. Jensen, E. Kaifer, A. M. Sargeson and A. C. Willis, Chem. Commun., 1996, 1649 DOI: 10.1039/CC9960001649
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