A novel B12 derivative 4 containing a peripheral thymine group is alkylated under reductive conditions with 2-bromo- methyl-2-methylmonothiomalonate 8 bearing the complementary adenine; photolysis in chloroform–acetonitrile gives the rearranged succinate 12 and dimethylmalonate 13 (2 : 1), whereas in MeOH–H2O only the dimethylmalonate 13 is formed.
T. Darbre, R. Keese and V. Siljegovic, Chem. Commun., 1996, 1561 DOI: 10.1039/CC9960001561
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
