Issue 8, 1996

Conflicting evidence regarding the mechanism of the sulfonyl transfer reaction

Abstract

Application of the novel solvent-dependent pKa method for the construction of Brønsted-type plots to the sulfonyl transfer reaction with phenoxide nucleophiles, finds the pKa's of aryloxides lower than those of the p-nitrophenoxide leaving group on separate lines, whereas nucleophiles of greater pKa fall on a common line, contrasting with the observed behaviour when using the traditional method.

Article information

Article type
Paper

Chem. Commun., 1996, 995-996

Conflicting evidence regarding the mechanism of the sulfonyl transfer reaction

S. Hoz, P. Liu and E. Buncel, Chem. Commun., 1996, 995 DOI: 10.1039/CC9960000995

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