Issue 8, 1996

Stereoselective additions to [60]fullerene

Abstract

1,3-Dipolar cycloaddition of chiral azomethine ylides to C60 affords mixtures of diastereoisomeric fulleropyrrolidines, which can be seperated by flash chromatography; the structure of the adducts is supported by unambiguous NOE enahancements, and CD curves of the adducts can be of help in the assignment of the absolute configuration.

Article information

Article type
Paper

Chem. Commun., 1996, 903-904

Stereoselective additions to [60]fullerene

F. Novello, M. Prato, T. Da Ros, M. De Amici, A. Bianco, C. Toniolo and M. Maggini, Chem. Commun., 1996, 903 DOI: 10.1039/CC9960000903

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