Issue 5, 1996

Gas hydrate-like pentagonal dodecahedral M2(H2O)18 cages (M = lanthanide or Y) in 2,5-dihydroxybenzoquinone-derived coordination polymers

Abstract

Ce2(dhbq)3·24H2O (dhbq2–= the dianion derived from 2,5-dihydroxybenzoquinone) contains gas hydrate-like pentagonal dodecahedral Ce2(H2O)18 cages which link together hexagonal grid Ce2(dhbq)3 sheets to form a three-dimensional network related to diamond and which pass through the Ce6(dhbq)6 rings of an independent, identical, interpenetrating diamond-related network.

Article information

Article type
Paper

Chem. Commun., 1996, 603-604

Gas hydrate-like pentagonal dodecahedral M2(H2O)18 cages (M = lanthanide or Y) in 2,5-dihydroxybenzoquinone-derived coordination polymers

B. F. Abrahams, J. Coleiro, B. F. Hoskins and R. Robson, Chem. Commun., 1996, 603 DOI: 10.1039/CC9960000603

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