Stoichiometric α- and β-phases of NiMoO4 show remarkable differences in the selective oxidation of butane to butenes and butadiene; modification of the surface acid–base properties of the catalysts by doping with K and Ca results in an increase in catalytic activity, especially with the α-phase.
M. F. Portela, R. M. Aranda, M. Madeira, M. Oliveira, F. Freire, R. Anouchinsky, A. Kaddouri and C. Mazzocchia, Chem. Commun., 1996, 501 DOI: 10.1039/CC9960000501
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