The activation of selenoglycosides is achieved by photo-induced electron transfer between aromatic compounds and the phenylselenyl group, while cleavage of the C–Se bond of the resulting radical cation generates a glycosyl cation that reacts with various alcohols to give the O-glycosides.
T. Furuta, K. Takeuchi and M. Iwamura, Chem. Commun., 1996, 157 DOI: 10.1039/CC9960000157
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