Treatment of a stable telluroketone with W(CO)5·thf affords the title compound, the X-ray crystal structure of which shows η1,σ-complexation and the trans influence of the weakly coordinated telluroketone; the regeneration of a ‘free’ telluroketone by ligand exchange of the complex under mild conditions is also reported.
M. Minoura, T. Kawashima, N. Tokitoh and R. Okazaki, Chem. Commun., 1996, 123 DOI: 10.1039/CC9960000123
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