Issue 1, 1996

Crystal engineering of metal complexes based on charge-augmented double hydrogen-bond interactions between thiosemicarbazides and carboxylates

Abstract

Charge augmented double hydrogen bonds have been used for the first time to form extended linear polymers between bis(thiosemicarbazide)nickel(2+) and dicarboxylate anions; the X-ray crystal structures of [Ni(tsc)2]2+[tere]2– 1 and [Ni(tsc)2(OH2)2]2[fum]2– 2 [tsc = thiosemicarbazide, H2NC(S)NHNH2; tere = terephthalate, C6H4(CO2)2-1,4; fum = fumarate, transO2CCH[double bond, length half m-dash]CHCO2] are discussed.

Article information

Article type
Paper

Chem. Commun., 1996, 97-99

Crystal engineering of metal complexes based on charge-augmented double hydrogen-bond interactions between thiosemicarbazides and carboxylates

A. D. Burrows, D. M. P. Mingos, A. J. P. White and D. J. Williams, Chem. Commun., 1996, 97 DOI: 10.1039/CC9960000097

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