13 C NMR investigations of [5,6]-NCO2R- and [5,6]-15NCO2R-bridged monoadducts of [60]fullerene obtained by the thermal reaction of [60]fullerene with azidoformates show that the transannular bond is open.
G. Schick, T. Grösser and A. Hirsch, J. Chem. Soc., Chem. Commun., 1995, 2289 DOI: 10.1039/C39950002289
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