Oxidation potentials Of [Mo2(ArNCHNAr)4](Ar = aryl), a direct measure of the HOMO (δ orbital) energy, correlate with the Hammett constant of aryl substituents, while both structural and spectroscopic data indicate that the valence structure around the dinuclear core is unperturbed.
C. Lin, J. D. Protasiewicz, E. T. Smith and T. Ren, J. Chem. Soc., Chem. Commun., 1995, 2257 DOI: 10.1039/C39950002257
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