A direct introduction of perfluorooctyl group into cycloalkanes using the photolysis of perfluoroazooctane upon 185 nm irradiation
Abstract
Perflucrooctyl-substituted cycloalkanes are prepared directly by photolysis of perfluoroazooctane in cycloalkanes upon 185 nm irradiation; a plausible mechanism is discussed on the basis of the time-course, quantum yield, and light intensity dependence during this photoreaction.