The curious positive effect of carbonaceous deposits on the skeletal isomerization of n-butenes over a H-FER zeolite can be related to the development of a new reaction mechanism involving as active sites tertiary carbenium ions blocked in the zeolite pores.
M. Guisnet, P. Andy, N. S. Gnep, C. Travers and E. Benazzi, J. Chem. Soc., Chem. Commun., 1995, 1685 DOI: 10.1039/C39950001685
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