1,2-Radical rearrangements of aryl, furanyl and thiophenyl groups from carbon to nitrogen using azido groups as radical precursors are observed for the first time; the 1,2-aryl rearrangement is applied to the synthesis of phenanthridine derivatives from 6-fluorenyl azides.
S. Kim and J. Y. Do, J. Chem. Soc., Chem. Commun., 1995, 1607 DOI: 10.1039/C39950001607
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