The synthesis of a bicyclic model of the calicheamicin/esperamicin aglycone is described using a highly efficient and stereospecific Nozaki–Kishi reaction for the ring closure.
I. Dancy, T. Skrydstrup, C. Crévisy and J. Beau, J. Chem. Soc., Chem. Commun., 1995, 799 DOI: 10.1039/C39950000799
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