An active site model for enzyme catalysed Baeyer–Villiger reactions is proposed and validated by transformation of the tricyclic ketone 6; Baeyer–Villiger reactions (and Baeyer–Villigerases) are classified by the stereochemistry of the hydroxyperoxide intermediate.
D. R. Kelly, C. J. Knowles, J. G. Mahdi, I. N. Taylor and M. A. Wright, J. Chem. Soc., Chem. Commun., 1995, 729 DOI: 10.1039/C39950000729
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