The 2,5-bis-(tert-butyl)phospholide anion promotes η5-complexation to late transition metals in cases where unhindered phospholyls may favour η1-ligation through the phosphorus lone pair.
D. Carmichael, L. Ricard and F. Mathey, J. Chem. Soc., Chem. Commun., 1994, 1167 DOI: 10.1039/C39940001167
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