Issue 11, 1994

X-Ray absorption spectroscopic study of the AlPO4-5: ferrocene inclusion compound and its thermally decomposed products

Abstract

The synthesis and decomposition of an inclusion compound, AlPO4: Fe(C5H5)2 is reported. This, and the decomposition products have been characterised by extended X-ray absorption fine structure spectroscopy. The clustering of iron atoms either through Fe—Fe or Fe—O—Fe interactions is shown to be absent. Instead, FeIII is sited within the double 6-rings of the 12-ring system. A model for distortions of the local lattice about FeIII is proposed.

Article information

Article type
Paper

J. Mater. Chem., 1994,4, 1723-1730

X-Ray absorption spectroscopic study of the AlPO4-5: ferrocene inclusion compound and its thermally decomposed products

A. Lund, D. G. Nicholson, G. Lamble and B. Beagley, J. Mater. Chem., 1994, 4, 1723 DOI: 10.1039/JM9940401723

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