The red luminescence of bismuth-doped alkaline-earth-metal sulfates is ascribed to the presence of divalent bismuth The optical transitions are due to transitions within the 6p shell.
M. A. Hamstra, H. F. Folkerts and G. Blasse, J. Mater. Chem., 1994, 4, 1349 DOI: 10.1039/JM9940401349
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