Intramolecular glycosylation of a pyrimidine derivative, which was temporarily connected to a 2,3-unsaturated 1-thiopentofuranoside through an ethereal linkage, led to an unusual 3′-isomeric nucleoside in a stereoselective fashion.
K. Sujino and H. Sugimura, J. Chem. Soc., Chem. Commun., 1994, 2541 DOI: 10.1039/C39940002541
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