Issue 20, 1994

Novel hydroperoxidation of the α-position in pyridoxylidene-amino acid Schiff base–cobalt complex by hydrogen peroxide

Abstract

The reaction of pyridoxylidene-L-phenylalanine with CoII ion in the presence of H2O2 generates a novel CoIII ternary complex, [Co(pyridoxylidene-α-hydroxyphenylalaninato)(pyridoxylidene-α- hydroperoxyphenylalaninato)], which has been characterized on the basis of the analysis of its 1H NMR, positive-ion FAB MS and X-ray structure.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2335-2336

Novel hydroperoxidation of the α-position in pyridoxylidene-amino acid Schiff base–cobalt complex by hydrogen peroxide

K. Jitsukawa, T. Yamamoto, T. Atsumi, H. Masuda and H. Einaga, J. Chem. Soc., Chem. Commun., 1994, 2335 DOI: 10.1039/C39940002335

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