Issue 13, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Dioxygen addition to five-coordinate osmium(II) complexes. X-Ray crystal structure of [OsH(η2-O2)(dcpe)2]bph4[dcpe = 1,2-bis(dicyclohexylphosphino)ethane]

Antonio Mezzetti,   Ennio Zangrando,   Alessandro Del Zotto  and  Pierluigi Rigo  

Abstract

The five-coordinate osmium(II) cations [OsX(dcpe)2]+[X = H or Cl; dcpe = 1,2-bis(dicyclohexylphosphino)ethane] react with dioxygen in 1 : 1 molar ratio giving the stable peroxo complexes trans-[OsX(O2)(dcpe)2]+.

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Article information

DOI
https://doi.org/10.1039/C39940001597
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1597-1598

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Dioxygen addition to five-coordinate osmium(II) complexes. X-Ray crystal structure of [OsH(η2-O2)(dcpe)2]bph4[dcpe = 1,2-bis(dicyclohexylphosphino)ethane]

A. Mezzetti, E. Zangrando, A. Del Zotto and P. Rigo, J. Chem. Soc., Chem. Commun., 1994, 1597 DOI: 10.1039/C39940001597

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