On exposure to UV light a crystal of diethyl (Z,Z)-hexa-2,4-dienediotate yielded an ultra-high molecular mass, highly stereoregular polymer, which was shown to have a tritactic structure by 13C NMR spectroscopy.
A. Matsumoto, T. Matsumura and S. Aoki, J. Chem. Soc., Chem. Commun., 1994, 1389 DOI: 10.1039/C39940001389
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