Electron addition at 77 K to cis-syn pyrimidine dimers yields the monomer radical anion directly, whereas the trans-syn dimer does not split, thus allowing the first observation of the undissociated dimer anion radical species.
I. D. Podmore, P. F. Heelis, M. C. R. Symons and A. Pezeshk, J. Chem. Soc., Chem. Commun., 1994, 1005 DOI: 10.1039/C39940001005
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