Issue 2, 1993
From the journal:

Journal of Materials Chemistry

Decamethylchromocenium tetracyanoethenide, (Cr(C5Me5)2]:.+[TCNE]˙+: a molecular ferromagnet with Tc= 3.65 K

Joel S. Miller,   R. Scott Mclean,   C. Vazquez,   Joseph C. Calabrese,   Fulin Zuo  and  Arthur J. Epstein  

Abstract

The electron-transfer salt 4[Cr(C5Me5)2]+[TCNE]˙–(TCNE = tetracyanoethylene) has been prepared and structurally characterized by single-crystal X-ray diffraction. It possesses a solid-state motif of parallel 1D chains of alternating radical rations and anions similar to, but not isostructural to, the ferromagnet [Fe(C5Me5)2]˙+[TCNE]˙–·4[Cr(C5Me5)2]+[TCNE]˙– is a soft ferromagnet with no hysteretic effects observed and Tc= 3.65 K.

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Article information

DOI
https://doi.org/10.1039/JM9930300215
Article type
Paper

J. Mater. Chem., 1993,3, 215-218

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Decamethylchromocenium tetracyanoethenide, (Cr(C5Me5)2]:.+[TCNE]˙+: a molecular ferromagnet with Tc= 3.65 K

J. S. Miller, R. S. Mclean, C. Vazquez, J. C. Calabrese, F. Zuo and A. J. Epstein, J. Mater. Chem., 1993, 3, 215 DOI: 10.1039/JM9930300215

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