Issue 23, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Ruthenium–dihydrogen complexes via C–H cleavage in alk-1-ynes. Crystal structure of [Ru(H2)(C[triple bond, length half m-dash]CPh}(dippe)2][BPh4][dippe = 1,2-bis(diisopropylphosphino)ethane]

Manuel Jiménez Tenorio,   M. Carmen Puerta  and  Pedro Valerga  

Abstract

The reaction of the monohydride complex [RuH(dippe)2]+ with alk-1-ynes yields the dihydrogen complexes [Ru(H2)(C[triple bond, length half m-dash]CR)(dippe)2]+(R = Ph or CO2Me); the X-ray crystal structure of [Ru(H2)(C[triple bond, length half m-dash]CPh)(dippe)2][BPh4] has been determined, and represents the first structural report of an alkynyl–dihydrogen complex.

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Article information

DOI
https://doi.org/10.1039/C39930001750
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1750-1751

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Ruthenium–dihydrogen complexes via C–H cleavage in alk-1-ynes. Crystal structure of [Ru(H2)(C[triple bond, length half m-dash]CPh}(dippe)2][BPh4][dippe = 1,2-bis(diisopropylphosphino)ethane]

M. J. Tenorio, M. C. Puerta and P. Valerga, J. Chem. Soc., Chem. Commun., 1993, 1750 DOI: 10.1039/C39930001750

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