Issue 22, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

The oxidation of ethane-1,2-diol resulting from molecular oxygen activation by copper: formation of an oxoethanoate complex precedes carbon–carbon bond cleavage

Maurizio Lanfranchi,   Laura Prati,   Michele Rossi  and  Antonio Tiripicchio  

Abstract

The aerial oxidation of ethane-1,2-diol in the presence of copper metal and pyridine (py) at room temperature and atmospheric pressure produces [Cu(py)2(HCO2)2]·H2O and [Cu2(py)4(OCH2CO2)2]·(CH2OH)2; the structure of the latter has been fully elucidated by an X-ray study.

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Article information

DOI
https://doi.org/10.1039/C39930001698
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1698-1699

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The oxidation of ethane-1,2-diol resulting from molecular oxygen activation by copper: formation of an oxoethanoate complex precedes carbon–carbon bond cleavage

M. Lanfranchi, L. Prati, M. Rossi and A. Tiripicchio, J. Chem. Soc., Chem. Commun., 1993, 1698 DOI: 10.1039/C39930001698

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