Dinuclear di-µ-hydroxozinc(II) complex 1, containing a tetradentate nitrogen ligand, readily absorbs atmospheric CO2 to form tri-zinc complex 2, containing an uncommon triply bridging carbonate group; the structures of 1 and 2 have been established by X-ray crystallography.
N. N. Murthy and K. D. Karlin, J. Chem. Soc., Chem. Commun., 1993, 1236 DOI: 10.1039/C39930001236
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