Issue 15, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

The use of the novel oxidising reagent triphenylarsine diiodine in the reaction with dicobalt octacarbonyl to produce a new type of complex [(Ph3Asl)2l][Co(AsPh3)l3]

Stephen M. Godfrey,   Helen P. Lane,   Anthony G. Mackie,   Charles A. McAuliffe  and  Robin G. Pritchard  

Abstract

Ph3AsI2 oxidises Co2(CO)8 in a 6 : 1 molar ratio to produce the novel complex [(Ph3AsI)2 I][Co(AsPh3)I3] in quantitative yield, the first crystallographically characterised complex containing a cobalt(II)-tertiary arsine bond and the unusual linear cation [Ph3As-I-I-I-AsPh3]+

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Article information

DOI
https://doi.org/10.1039/C39930001190
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1190-1191

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The use of the novel oxidising reagent triphenylarsine diiodine in the reaction with dicobalt octacarbonyl to produce a new type of complex [(Ph3Asl)2l][Co(AsPh3)l3]

S. M. Godfrey, H. P. Lane, A. G. Mackie, C. A. McAuliffe and R. G. Pritchard, J. Chem. Soc., Chem. Commun., 1993, 1190 DOI: 10.1039/C39930001190

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