The first silica-pillared titanoniobate has been prepared by firstly intercalating layered titanoniobate with NH2(CH2)3Si(OEt)3 and subsequently thermally removing the interlayered organics, the resulting pillared material is porous and has a high thermal stability beyond 750 °C.
W. Hou, J. Ma, Q. Yan and X. Fu, J. Chem. Soc., Chem. Commun., 1993, 1144 DOI: 10.1039/C39930001144
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