Base-catalysed dehydrohalogenation of a 3,18-bis(2-ohloroethyl)biliverdin 1 affords a novel 3-vinylbiliverdin 3 in which the 2- and 18-positions are bridged with a propano-tether; the structure of 3 has been established using single crystal X-ray and 1H nuclear Overhauser effect studies.
E. D. Sturrock, J. R. Bull, R. E. Kirsch, R. K. Pandey, M. O. Senge and K. M. Smith, J. Chem. Soc., Chem. Commun., 1993, 872 DOI: 10.1039/C39930000872
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