Issue 9, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

C–H allylic bond cleavage to generate an active hydridopalladium species for the alkoxycarbonylation of alkenes. X-Ray crystal structure of [(Ph3PCH2CH[double bond, length half m-dash]CHPh)4(PdCl6)(SnCl6)]

Thomas Chenal,   Ruth Naigre,   Isabelle Ciprés,   Philippe Kalck,   Jean-Claude Daran  and  Jacqueline Vaissermann  

Abstract

On the basis of a reactivity study using various alkenes and of the X-ray crystal structure analysis of the title compound isolated from the alkoxycarbonylation reaction, the formation of an active Pd(H)(SnCl3) species, generated from the [PdCl2(PPh3)2]SnCl2–PPh3 system, is proposed.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39930000747
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 747-750

Permissions

Request permissions

C–H allylic bond cleavage to generate an active hydridopalladium species for the alkoxycarbonylation of alkenes. X-Ray crystal structure of [(Ph3PCH2CH[double bond, length half m-dash]CHPh)4(PdCl6)(SnCl6)]

T. Chenal, R. Naigre, I. Ciprés, P. Kalck, J. Daran and J. Vaissermann, J. Chem. Soc., Chem. Commun., 1993, 747 DOI: 10.1039/C39930000747

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements