The anti-herpes agent carbocyclic oxetanocin-A (–)-2 has been prepared from the bicyclic ketone 3via resolution of the bromohydrin 4(using an enzyme-catalysed trans-esterification reaction) and a photocatalysed rearrangement of the epoxide (+)-6 to the lactone (+)-7.
I. C. Cotterill and S. M. Roberts, J. Chem. Soc., Perkin Trans. 1, 1992, 2585 DOI: 10.1039/P19920002585
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