The uncatalysed Diels–Alder addition of 1 -(trimethylsilyloxy)- and 1 -acetoxybuta-1,3-diene to a sugar-derived nitroalkene proceeds with complete regioselectivity and diastereofacial selectivity to yield crystalline, optically pure, cyclohexene derivatives.
J. A. Serrano, L. E. Cáceres and E. Román, J. Chem. Soc., Perkin Trans. 1, 1992, 941 DOI: 10.1039/P19920000941
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