The synthesis of [Mo(η-C7H7)(η-C7H9)] from MoCl5 provides a convenient route to η-cycloheptatrienylmolybdenum compounds such as [Mo(η-C7H7)LX2] and [Mo(η-C7H7)L2X], where L = tertiary phosphines or acetonitrile and X = halogen, and [Mo(η-C7H7)(η-C5H4R)], R = H, Me.
M. L. H. Green, D. K. P. Ng and R. C. Tovey, J. Chem. Soc., Chem. Commun., 1992, 918 DOI: 10.1039/C39920000918
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