In the presence of transition metal (Fe, Rh) catalysts, CO2 can modulate the oxidative properties of O2 towards tetrahydrofuran (THF) and styrene; the intermediate formation of metal-peroxocarbonate species, [Ln[graphic omitted]], seems to play a key role in these processes.
M. Aresta, C. Fragale, E. Quaranta and I. Tommasi, J. Chem. Soc., Chem. Commun., 1992, 315 DOI: 10.1039/C39920000315
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