Issue 4, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and molecular structures of the sandwich anion [K(18-crown-6)][Nb(η-C7H7)(η-C5H5)] and cation [Nb(η-C7H7)(η-C5H4Me)(thf)]PF6

Malcolm L. H. Green,   Philip Mountford,   Victor S. B. Mtetwa,   Peter Scott  and  Stephen J. Simpson  

Abstract

The 17-electron compounds Nb(η-C7H7)(η-C5H4R) undergo reversible one-electron oxidation and reduction giving the structurally characterised compounds [Nb(η-C7H7)(η-C5H4Me)(thf)]PF6 and [K(18-crown-6)][Nb(η-C7H7)(η-C5H5)] respectively; the latter has an unusual distorted chain structure.

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Article information

DOI
https://doi.org/10.1039/C39920000314
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 314-315

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Synthesis and molecular structures of the sandwich anion [K(18-crown-6)][Nb(η-C7H7)(η-C5H5)] and cation [Nb(η-C7H7)(η-C5H4Me)(thf)]PF6

M. L. H. Green, P. Mountford, V. S. B. Mtetwa, P. Scott and S. J. Simpson, J. Chem. Soc., Chem. Commun., 1992, 314 DOI: 10.1039/C39920000314

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