Issue 2, 1992

Synthesis, reactivity and X-ray crystallographic characterization of chloro(propan-2-ol)bis(tetraisopropoxoaluminato)praseodymium(III) dimer, [{Pr[Al(OPri)4]2(PriOH)(µ-Cl)}2]

Abstract

The product of the 1 : 2 reaction between PrCl3·3PriOH and K[Al(OPri)4] in benzeno–propan-2-ol, has been shown by X-ray crystallographic analysis to be a heptacoordinated heteroleptic alkoxometallatopraseodymium(III) complex 1, which affords solvated and unsolvated species respectively by ligand displacement reactions and distillation in vacuo.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 152-153

Synthesis, reactivity and X-ray crystallographic characterization of chloro(propan-2-ol)bis(tetraisopropoxoaluminato)praseodymium(III) dimer, [{Pr[Al(OPri)4]2(PriOH)(µ-Cl)}2]

U. M. Tripathi, A. Singh, R. C. Mehrotra, S. C. Goel, M. Y. Chiang and W. E. Buhro, J. Chem. Soc., Chem. Commun., 1992, 152 DOI: 10.1039/C39920000152

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