Allenyl(aryl)iodinanes, generated from p-methoxy(diacetoxyiodo)arenes by the reaction with propyn-2-yl(trimethyl)silanes in the presence of BF3–Et2O in dichloromethane, undergo reductive ipso iodonio-Claisen rearrangement selectivity at –20 °C yielding ipso-substituted propynylarenes.
M. Ochiai, T. Ito and Y. Masaki, J. Chem. Soc., Chem. Commun., 1992, 15 DOI: 10.1039/C39920000015
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...