The electron-transfer salt 3[Mn(C5Me5)2]:+[DDQ]˙–, isomorphous to orthorhombic [Fe(C5Me5)2]˙+[DDQ]˙–, has been prepared. It exhibits a complex field-dependent magnetic pahse diagram at low temperatures with evidence for ferromagnetic coupling as well as a low moment state below 4 K for zero-field cooled samples.
J. S. Miller, R. S. McLean, C. Vazquez, G. T. Yee, K. S. Narayan and A. J. Epstein, J. Mater. Chem., 1991, 1, 479 DOI: 10.1039/JM9910100479
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